4-Bromo-2-(4-fluorobenzylidene)indan-1-one

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4-Bromo-2-(4-fluoro­benzyl­idene)indan-1-one

In the mol-ecule of the title compound, C(16)H(10)BrFO, the indane ring system is planar with a maximum deviation of 0.020 (3) Å. An intra-molecular C-H⋯O inter-action results in the formation of a planar ring, which is oriented at dihedral angles of 2.24 (3) and 2.34 (3)° with respect to the adjacent rings. π-π contacts between the benzene and indane rings [centroid-centroid distances = 3.699 ...

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Planar (r.m.s. deviation from the plane through all non-H atoms = 0.036 Å) mol-ecules of the title compound, C(16)H(11)BrO(2), form a layered structure stabilized by C-H⋯O hydrogen bonds and π-π stacking inter-actions.

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4-Bromo-2-[1-(4-eth­oxy­phen­yl)-1-methyl­eth­yl]-1-methyl­benzene

In title compound, C(18)H(21)BrO, the dihedral angle between two rings is 85.72°. No classical hydrogen bonds are found and only van der Waals forces stabilize the crystal packing.

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(2E)-3-(3-Bromo-4-meth­oxy­phen­yl)-1-(4-fluoro­phen­yl)prop-2-en-1-one

In the title compound, C(16)H(12)BrFO(2), the dihedral angle between the aromatic rings is 23.75 (12)° and the dihedral angle between the prop-2-en-1-one fragment and the fluorobenzene ring is 20.9 (2)°. In the crystal, only van der Waals interactions occur.

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(2E)-3-(3-Bromo-4-meth­oxy­phen­yl)-1-(4-methyl­phen­yl)prop-2-en-1-one

The overall shape of the mol-ecule of the title compound, C(17)H(15)BrO(2), can be described by the dihedral angles between three planar fragments: 1-bromo-2-meth-oxy-phenyl ring [maximum deviation = 0.003 (2) Å], the central prop-2-en-1-one chain [maximum deviation = 0.005 (2) Å], and the methyl-phenyl ring [maximum deviation = 0.004 (2) Å]. The terminal planes are twisted by 10.37 (12)°, whil...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809025781